Oil
Spill Detection on Sea Water Using AVIRIS Data
Submerged
Aquatic Vegetation Remote Sensing
Oil Spill Detection on Sea Water
Using AVIRIS Data
Project Leader: Dr. M. Kafatos (L) and Ms. Foudan Salem, GMU
Background:
Our applied research will assess the detection of oil
spills on freshwater and seawater using hyperspectral image analysis,
AVIRIS data, and information available for spills in other areas, such
as in Santa Barbara, California. In earlier research, the Patuxent River
in Maryland, was selected as a prototype for oil spill detection in
the relatively calm waters of Chesapeake Bay.
Technical Approach:
Now we plan to use AVIRIS data to study ocean spills as evidenced in
the Santa Barbara coastline. The reason for selecting this western coastal
zone is that features on the surface make the study more realistic and
useful to other costal area applications in Virginia. The detection
of an oil slick affected by heavy seas and breaking waves will be different
than oil on flowing river waters. The Santa Barbara coastal area will
be used for creating oil mitigation simulations and scenarios.
AVIRIS DATA SETS
The AVIRIS (Airborne Visible/Infrared Imaging Spectrometer) is a unique
optical sensor that delivers calibrated images of the spectral radiance
in 224 contiguous spectral channels (bands) with wavelengths from 400
to 2500 nanometers. The main objective of using the AVIRIS data is to
identify, measure, and monitor constituents of oil spills based on molecular
absorption and particle scattering signatures.
The measurements can be converted to ground reflectance
data which can then be used for quantitative characterization of surface
features. Compared with the AISA sensor used before, the classification
processes in the first part of this study was done using 25 bands, which
were not useful in spectral matching with different spectral libraries,
because of it’s wavelength range from 400 to 800 nanometers. The
AVIRIS sensor will allow more specific spectral analysis with wavelengths
from 400 to 2500 nanometers and 224 bands.
The AVIRIS scene of the Santa Barbara coast will be
obtained from Jet Propulsion Laboratory, Caltech, (JPL/ NASA).

METHODOLOGY
From our own experience and the literature on the spectral properties
of various types of oil, we knew that the HSI would see sheens and oil
slicks, but we could find no reports in the literature of the spectral
properties of oil dispersed with chemical dispersants. If a distinctive
spectral signature could be found for the dispersant itself and the
dispersed oil, then algorithms could be developed which would optimize
the identification and tracking of both. Also, we can obtain operational
experience and assess the utility of airborne hyperspectral remote sensing
with AVIRIS over an oil spill in preparation for other disasters elsewhere.
This activity includes the following tasks
- Compare ”pure” oil spectra from the data sets (AISA
and AVIRIS)
- Collect oil spectral information for different oil types and dispersed
oil on the sea water
- Determine the optimal spectral bands for detection of this type
of oil and dispersant
- Perform accuracy assessments for multi spectral and hyperspectral
data sets
- Compare other polluted water spectra (fresh water versus sea water)
- Run current Spectral Angle Mapper (SAM) classifications for the
Santa Barbara scene
- Apply the Mixture Tuned Matched Filtering (MTMF) method to AVIRIS
data and compare the results with existing methods for spectral analysis
- Use hyperspectral data over land in an attempt to map the effects
of soiling of coastal zones and sandy beaches and providing baseline
data for long term monitoring of the impact of oil pollutants.
Milestones:
3rd Quarter Assessment of oil detection in seawater analyses

Submerged Aquatic Vegetation Remote Sensing
Project Leader: Dr. Richard Gomez, GMU
Background
It is well established that submerged aquatic vegetation
(SAV) is an important part of the food chain in Chesapeake Bay, providing
shelter and nursery areas for shellfish and finfish and food for a variety
of waterfowl, fish, and invertebrates. There has been a series of massive
declines observed in SAV covered areas in the Chesapeake Bay, which
are of serious concern to scientists and resource managers even with
an increase in restoration efforts, as well as increased limited area
coverage that has occurred in recent years. Remote sensing of the Chesapeake
Bay SAV ecosystem could be very valuable in establishing trends in areal
coverage and could potentially be used to identify the species of SAV
growing in particular areas. The tidal Potomac River and Estuary provide
an ideal ecosystem for applied research leading to the restoration of
SAV baywide.
In support of this project, GMU is continuing the development
of a spectral library database containing selected ground-based and
airborne sensor SAV spectra for use in image processing. The long-term
goal of the spectral database is to automate the image processing of
hyperspectral imagery for potential real-time material identification
and mapping of SAV. Further research into the spectral signatures of
various SAV species with a focus on bio-chemical differences is contemplated.
For this year, the spectral library database for removing potential
false positives and mapping SAV by species will be made more effective
and computationally efficient. The Spectral Library SAV Information
System will also serve as a tutorial capability to train people in the
use of this hyperspectral technology for SAV identification and mapping.
George Mason University (GMU) was part of the team
that investigated the use of airborne hyperspectral remote sensing imagery
for automated mapping of submersed aquatic vegetation in the tidal Potomac
River for near to real-time resource assessment and monitoring [1].
In that investigation, field surveys at the tidal Potomac River at the
mouth of Nanjemoy Creek at Blossom Point, in southern Charles County
Maryland, determined SAV presence, species, and distribution. Airborne
hyperspectral imagery, using the HyMap sensor, together with in-situ
spectral reflectance measurements using a field spectrometer, were obtained
for the pilot sites in spring and early fall of 2000. A spectral library
database, which currently resides at GMU containing selected ground-based
and airborne sensor spectra, is being developed for use in hyperspectral
image processing of SAV. The goal of the spectral database is to automate
the image processing of hyperspectral imagery for potential real-time
material identification and mapping of SAV. Field based spectra were
compared to the airborne imagery using the database to identify and
map two species of SAV (Myriophyllum spicatum and Vallisneria mericana).
Of the seventeen species of submerged aquatic vegetation that are commonly
found in the Chesapeake Bay and its tributaries, these two are among
the most abundant. Overall accuracy of the vegetation maps derived from
hyperspectral imagery was determined by comparison to a product that
combined aerial photography and field based sampling at the end of the
SAV growing season. Map accuracy was high and had very low false positive
detections. The algorithms and databases developed in this study will
be useful with the investigation under this proposed VAccess project,
the main objective, which is to prepare the remote sensing and terrestrial
ecology communities for exploiting current and forthcoming space-based
hyperspectral remote sensing systems.
METHODOLOGY
Imaging spectroscopy, also called hyperspectral imaging (HSI), was originally
developed by astronomers to obtain geochemical data from inaccessible
planetary surfaces within the solar system [2]. The primary application
of this technology has now shifted to the observation of the Earth with
airborne and spaceborne hyperspectral remote sensors. AVIRIS and Hyperion
are good examples, respectively. The basis of traditional remote sensing
theory involves the interaction of electromagnetic radiation with materials
on a “macroscopic” level, including reflection, refraction,
diffraction, absorption, and scattering effects [2]. The emerging enabling
technology known as hyperspectral imagery, places emphasis on the “microscale”
monitoring interactions of electromagnetic energy within molecules,
crystal lattices, and cell structures [2,3]. This new perspective requires
knowledge of quantum mechanics and a “particulate” view
of electromagnetic energy [2]. Ecological research, in particular, is
likely to benefit rapidly from the increased spectral resolution that
hyperspectral sensors can provide. Most natural Earth surface and water
materials have diagnostic absorption features in the range of current
hyperspectral sensors, i.e., 400 nm – 2500 nm range of the reflected
spectrum. With the diverse chemistry of the materials involved, spectral
signatures can be complex and sometimes difficult to interpret. However,
with the increasing knowledge of the spectral signatures involved, this
problem will continue to diminish. Roger N. Clark [4] suggests that
the previous disadvantage, for imaging spectroscopy, is turning into
a huge advantage, allowing us to probe ever more detail about the chemistry
of our natural environment.

The ecological activities of the project will be conducted
in phases, and most of the fieldwork will be conducted on the Chesapeake
Bay. The principal submerged aquatic vegetation (SAV) species for the
Chesapeake Bay are Eurasian watermilfoil (Myriophyllum spicatum) and
wildcelery (Vallisneria mericana). Keep in mind that we will use archived
data during the first year of this ecology research part of the project
(Phase 1). The first phase of the field research focuses on assuring
the calibration of the HSI methodology for the two dominant SAV species.
At three times during the growing season (late spring, mid summer and
early fall), in situ measurements will be made with an Analytical Spectral
Devices, Inc (ASD) field portable spectroradiometer provided by VAccess.
(See Figure 9). This Field Spectrometer has a 350 to 1050 nanometers
spectral range that will be fully used. The in situ measurements over
several windows of time will allow for the calibration to identify (i)
age-dependent changes in spectral properties and (ii) site-specific
affects on spectral properties. The former, which has been reported
in an earlier study by one of the principal investigators [1], is attributed
to epiphytic colonies of microbes and appears to be minor. The second
class of factors is related to covariates associated with the water
column (e.g., turbidity, depth). Harvesting of plant samples during
each trip and re-testing under controlled laboratory conditions in the
Physiological Ecology Laboratory on the George Mason University campus
will be used to further investigate these in situ calibration records.
The resulting data (in situ and laboratory) will be used to populate
the team’s HSI spectral library database.
Technical Approach
The research will be divided into two phases, a demonstration
phase and a validation phase. The use of a demonstration phase will
allow for research to begin immediately through the use of archived
imagery. A demonstration phase will also allow us to better define all
the required steps in the validation phase, thus significantly increasing
the chances of a successful research effort. Validation of the demonstration
phase results will be performed in phase 2, using new collections that
will take place during the demonstration phase with the new imagery
being available for the start of the validation phase.
Demonstration phase: In this phase, the ecology application
to be addressed will be better defined. We will determine which ecology
applications are appropriate for remote sensing technologies. Several
applications will be addressed. Data requirements (for both demonstration
phase with archived data and validation phase with new imaging collections)
will be established. We will identify one site for the demonstration
phase using archived data. The 2nd site will be identified for validation
phase using new collections (the two sites may possibly be the same).
We will collect imagery, ground truth, and other data. We will use HyMap
data for this phase and any other data we may find. It is possible that
Hyperion data might be available.
Validation Phase: During the validation phase, GPS will be used when
collecting spectral truth (we will also collect GPS points at road intersections,
building corners, parking lots, etc). Data collected over the pilot
sites during the demonstration phase will be used for the validation
of the specialized tools for analysis of SAV data. The data collection
effort will continue through the second and third years.
Milestones
The main goal of the proposed project will be to perform
analysis of hyperspectral data to better understand the Chesapeake Bay
submerged aquatic vegetation (SAV) ecosystem variability and responsiveness
to global change.
A spectral library populated with spectral signatures
for all SAV species found at the Chesapeake Bay pilot site will be developed
and will be made available to the community through the Internet. The
data will come from various sources including the laboratory and field
measurements done under this project.
References
1. D. J. Williams, T. M. O’Brien, N. B. Rybicki, A. V. Lombana,
and R. B. Gomez, “Preliminary Investigations of Submerged Aquatic
Vegetation Mapping using Hyperspectral Remote Sensing”, to be
published in Environmental Monitoring and Assessment, Springer-Vertag,
2002.
2. A.F.H.Goetz (1992), “Imaging Spectrometry for Earth Remote
Sensing”, in Imaging
Spectroscopy: Fundamentals and Prospective Applications, F. Toselliand
J. Bodechtel, Eds., 1-19, Brussels and Luxembourg.
3. K. Nassau (1983), The Physics and Chemistry of Color – The
Fifteen Causes of Color, Wiley Interscience.
4. R.N. Clark (1999), “Spectroscopy and Principles of Spectroscopy
Manual of Remote Sensing, A. Rencz, Editor, John Wiley and Sons, Inc.
